This study investigates the impact of bottom-up casting on the bond behaviour between reinforcing steel and self-compacting concrete in full-scale structural wall elements. Through experimental pull-out tests and X-ray computed tomography, a comparison is made between bottom-up casting and the conventional top-down method. A wall-type test element measuring 2240×1600×160 mm was designed for the study. The results obtained from this study demonstrate that bottom-up casting technology significantly enhances bond strength, showing a 10% increase in normalised bond strength. This improvement in bond strength is attributed to enhanced consolidation and deaeration of the mix during the casting process, which serves to minimise defects such as air voids. Additionally, the bottom-up method leads to more uniform bond distribution along the height of the wall, thereby reducing the top-bar effect commonly seen in top-down casting. Tomographic scans revealed a reduced presence of air voids in the cover zone of bottom-up cast elements, providing further evidence of superior material compaction. The study concludes that bottom-up casting holds promise for improving SCC element performance, especially in applications where bond quality and uniformity are critical.