Permeable concrete has the characteristics of breathability, permeability, and high heat dissipation. To improve its mechanical and frost resistance properties, this study optimized the preparation and performance of permeable concrete by adding materials to improve its performance. The performance analysis validate that epoxy resin owns a filling effect on the pores of permeable concrete. The internal curing agent, high water absorbent resin, has a good water absorption effect. The synergistic effect of these two increases the density and compressive strength of permeable concrete. When the two contents are 0.5%, the maximum compressive strength of modified permeable concrete at 7 and 28 days was 15.62 and 17.97 Mpa, respectively. Under the action of freeze-thaw cycles, its mass loss rate show an upward trend By comparison, epoxy resin and high water absorbent resin are beneficial for improving the frost resistance of permeable concrete. The minimum value of relative dynamic modulus of elasticity remains stable at over 80%, and the loss rate of dynamic modulus of elasticity is all below 0.4. However, the influence of epoxy resin and SAP on the mass loss rate is relatively small, and the mass loss of all experimental groups is controlled below 2.5%. The binomial Fourier function model is the best predictive model for permeable concrete under freeze-thaw cycles. This study has positive significance for improving the performance of permeable concrete and maintaining the sustainable development of ecological cities.